화학공학소재연구정보센터
Polymer Bulletin, Vol.43, No.4-5, 403-408, 1999
Graft polymerization of N,N-dimethylaminoethylmethacrylate onto polycarbonates by the preirradiation method
Radiation-induced graft polymerization of N,N-dimethylaminoethylmethacrylate (DMAEMA) from solutions in carbon tetrachloride or in chloroform onto bisphenol A-derived polycarbonate (PC-1) and allyl diglycol carbonate (PC-2), respectively, was carried out by method of preirradiation in air. It has been found essential difference in transparency and durability of the modified PC-1 and PC-2. Effects of preirradiation dose as well as temperature and time of graft polymerization on effectiveness of DMAEMA grafting onto PC-2 were investigated, the optimal values of dose and temperature are 500 kGy and 55 degrees C, respectively.