Polymer Engineering and Science, Vol.38, No.4, 674-688, 1998
Microcellular sheet extrusion system process design models for shaping and cell growth control
The feasibility of shaping a nucleated polymer/gas solution represents a significant advancement for microcellular plastics process technology. Through proper design of the foaming die, nucleated solution flows can be shaped to arbitrary dimensions while maintaining the functional independence of cell nucleation, cell growth and shaping. To maintain functional independence, stringent pressure and temperature design specifications, which supersede those of conventional foam processing, must be met by the foaming die design. As a means of aiding the design process, a model is developed for predicting pressure losses and flow rates of nucleated polymer/gas solutions. A comparison of the model predictions and the actual foaming die design performance shows good agreement for limited data. These relatively simple models capture the major physics of the complicated two-phase now field and provide a sound base from which scale-up of the foaming die concept can be achieved. The nucleated polymer/gas solution flow models predict highly nonlinear volumetric flow rates contrasting constant flow rates predicted for the neat polymer now. In addition, a convenient method for classifying nucleated polymer/gas solution flow is presented based on a dimensionless ratio of the characteristic flow rate to the characteristic gas diffusion rate.
Keywords:BUBBLE-GROWTH;SEMICRYSTALLINE STATES;FOAM GROWTH;POLY(ETHYLENE-TEREPHTHALATE);DYNAMICS;NUCLEATION