화학공학소재연구정보센터
Polymer Engineering and Science, Vol.38, No.7, 1060-1071, 1998
An experimental study on the effect of polymer viscoelasticity on layer rearrangement in coextruded structures
Previous work on the layer thickness uniformity of coextruded structures has centered primarily on the effects of differing polymer viscosities in the individual layers. These differences in viscosities result in a phenomenon known as 'viscous encapsulation" in which the less viscous layer tends to encapsulate the more viscous layer producing nonuniform layer thicknesses. In this study, the effect of polymer viscoelasticity on the layer thickness uniformity of multilayer coextruded structures was investigated by coextruding multilayer structures through die channels of different cross-sectional shapes and observing the location of the interface. In order to minimize the viscosity effects, the coextrusion experiments were conducted with identical materials in each layer that were pigmented to allow observation of the layer interface. It was shown experimentally that coextruding identical polymers through channels of various geometries can cause the layers to rearrange. This layer rearrangement appears to be caused by secondary flows that occur in different channel geometries due to the viscoelastic characteristics of the polymer. Layer rearrangement of identical polymers implies that even resins with viscosities well matched for coextrusion may experience nonuniform layer thicknesses when coextruded through large dies.