Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer

Gil S; Gonzalez R; Mestres R; Sanz V; Zapater A

Reactive & Functional Polymers, Vol.42, No.1, 65-72, 1999

DOI10.1016/S1381-5148(98)00056-X Export Citation

Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer

Gil S, Gonzalez R, Mestres R, Sanz V, Zapater A

High conversion and epoxide selectivity from alkenes is achieved with tert-butyl hydroperoxide and a polystyrene-grafted Mo(VI) catalyst, with no noticeable leaching of Mo from the support.

Keywords:IMIDAZOLE-CONTAINING POLYMERS;ALKYL HYDROPEROXIDES;OLEFINEPOXIDATION;COMPLEXES;CYCLOHEXENE;MOLYBDENUM;PEROXIDE