Revue de l Institut Francais du Petrole, Vol.50, No.5, 611-625, 1995
Hydrates problem within the framework of multiphase production and transport of crude oils and natural gases .2. Possible solutions to exploitation difficulties generated by hydrates
Offshore exploitation of fossil fluid fuels has emphasized the need of improving our knowledge on hydrates which can plug production, treatment and transport facilities. The first part(*) recalled the molecular structure of I, II and H hydrates, then the physical-chemistry of their formation was briefly reviewed from both the thermodynamic and the kinetic points of view. In this second part, the possible remedies to the problems met by operating companies are described, mainly classical thermodynamic inhibitors such as alcohols or salts which decrease the hydrates formation temperature, and dispersant additives which avoid crystals growth and/or agglomeration. At last an original circulation loop at pilot scale is presented, its characteristics which allow the testing of dispersant additives under representative hydrodynamic and physico-chemical conditions being outlined.