화학공학소재연구정보센터
Rheologica Acta, Vol.35, No.3, 225-232, 1996
Linear viscoelastic behavior of the Hookean dumbbell with internal viscosity
The linear viscoelastic modulus G(t) predicted by the analytical formulations of Schieber (1993), Wedgewood (1993), Dasbach et al. (1992), and Booij and van Wiechen (1970) for the free-draining Hookean dumbbell with internal viscosity (IV) are compared with exact analytical results and exact numerical results obtained from Brownian dynamics simulations. All of these analytical formulations employ the Booij and van Wiechen expression for the IV force, thereby eliminating errors associated with linearization of the ''deformational'' velocity, however the theories differ in the approximations employed to solve configuration moment equations. Comparison with the exact G(t) results provides a means of testing these approximations. The approximate theories all correctly predict the singular part of G(t) at t = 0, providing correct predictions of eta(infinity)' however deviations from the exact G(t) are seen in all cases for t > 0.