Science, Vol.275, No.5296, 60-61, 1997
A Free Cyclotrigermenium Cation with a 2-Pi-Electron System
The reaction of tetrakis(tri-tert-butylsilyl)cyclotrigermene with trityl tetraphenylborate in benzene produces tris(tri-teri-butylsilyl)cyclotrigermenium tetraphenylborate [(tert-Bu(3)SiGe)(3)(+)BPh(4)(-)], which can be isolated as a yellow solid that is stable in the absence of air. The crystal structure of the cyclotrigermenium ion reveals a free germyl cation with a 2 pi-electron system. The three germanium atoms form an equilateral triangle similar to the carbon analog, the cyclopropenium ion.
Keywords:SILICON DOUBLE-BOND;AB-INITIO IGLO;TRIETHYLSILYL CATIONS;MOLECULAR-STRUCTURE;SILYLIUM CATIONS;IONS;CHEMISTRY;CRYSTAL;ANALOGS;SEARCH