Distillation experiments were carried out on three binary systems (ethanol-butanol, ethanol-propan-2-ol, and propan-2-ol-butanol) in a 0.1-m internal diameter glass column packed with 8 mm diameter Raschig rings. The experiments were performed under total reflux conditions and at atmospheric pressure. The data collected on column performance showed that performance declined with increasing average bulk liquid density. The results also lend credence to earlier reports on the behavior of column performance with respect to component concentration in the feed mixtures. The system densities of the three binary systems were measured at four different temperatures, 30, 40, 50, and 60 degrees C. The data were compared with the predicted data of Yen-Woods and Multifluid models. The accuracy of the predictions of the Yen-Woods model was rather poor while that of the Multifluid model was very encouraging.