The structure of glasses prepared in the Na2O-Ga2O3-P2O5 system was investigated by vibrational (IR, Raman) and X-ray absorption spectroscopies. For the orthophosphate compositions, gallium is found in four-fold coordination, whereas it is found in six-fold coordination in a metaphosphate glass. For pyro-, tri and tetraphosphate glasses, gallium atoms are distributed on tetrahedral and octahedral sites. Gallium atoms found on octahedral sites are likely chelated by pyrophosphate groups. The ionic conductivity of the glasses depends mainly on their sodium content.