Solid State Ionics, Vol.86-88, 653-658, 1996
Defect Model of Proton Insertion into Oxides
The pertinent equations governing proton incorporation in oxides with special emphasis on high temperature proton conductors (HTPCs) are reviewed. The prototypical compound SrCe0.95Yb0.05O3-alpha is considered in detail. Different domains in the key parameters p(H2O) and p(O2) can be distinguished, where essentially one defect type balances the dopant concentration in the electroneutrality condition. A predominance diagram is presented where these domains are outlined. The transitions between the domains occur at critical pressures p*(H2O), p*(H2), p**(H2), p*(O2) and p**(O2) which are given by the equilibrium constants and the dopant concentration. By introducing new dimensionless variables such as p(H2O)/p*(H2O) it is shown that the whole process of proton incorporation can be described by one master curve which displays Sieverts-type behavior at low pressures and saturation at higher pressures of H2O. A similar diagram as above but incorporating conductivity data is also presented.
Keywords:YB-DOPED SRCEO3;HYDROGEN