Solid State Ionics, Vol.101-103, 585-589, 1997
Ferroelastic phase transition, domain pattern and metastability in diluted lead phosphate-type crystals
Dilution of the lead positions in improper ferroelastic lead phosphate and lead arsenate by cations without lone pair electron leads to strong re-normalization phenomena. The influence of Ba and Sr impurities on the transition behaviour is studied using optical birefringence, synchrotron X-ray diffraction and diffuse scattering. W and W' twin-walls appear in metastable ferroelastic phases where structural modulations with long lifetime show isothermal relaxations. Strain-induced order parameter coupling is observed in (Pb1-xBax)(3)(AsO4)(2).
Keywords:(PB1-XBAX)(3)(PO4)(2);PB3(PO4)2