Solid State Ionics, Vol.117, No.3-4, 323-330, 1999
High-temperature deformation of BaCe1-xYxO3-y (0.05 <= x <= 0.2)
Compressive high-temperature deformation of BaCe1-xYxO3-y polycrystals as a function of yttrium content (x = 0.05, 0.1, 0.15, and 0.2) was conducted in controlled oxygen partial pressures of 0.1-2 X 10(4) Pa at 1200-1400 degrees C to determine deformation kinetics and the rate-controlling species for diffusional creep. Creep rate was independent of oxygen partial pressure and the steady-state creep rate increased with increasing Y content. The results can be explained on the basis of a grain-boundary-sliding creep mechanism in which the rate-controlling species are Ba or Ce interstitials. A simple point-defect model was used to describe the results.
Keywords:DIFFUSIONAL CREEP;TRANSPORT-PROPERTIES;SOLID-ELECTROLYTE;COMPRESSIVE CREEP;CONDUCTION;YBA2CU3OX;OXIDES;PROTON