Thermochimica Acta, Vol.228, 271-281, 1993
Determination of Kinetic-Parameters for the Reoxidation of Direct Reduced Iron Under Rising Temperature Conditions
This paper presents the main kinetic parameters for the reoxidation of direct reduced iron (DRI) samples in air under non-isothermal conditions and compares the data with isothermal kinetic parameters for a typical DRI sample. It is found that the non-isothermal activation energy (DELTAE) values are less than the isothermal DELTAE values. For coal based DRI, the non-isothermal DELTAE values lie in the range 20-35 kJ mol-1. For gas based DRI the value is much higher, about 55 kJ mol-1. For the reoxidation of DRI, the kinetic compensation effect (KCE) has been found to be valid.