화학공학소재연구정보센터
Thermochimica Acta, Vol.230, 143-153, 1993
Kinetic-Analysis of Thermal-Decomposition Reactions .8. Radiation Effects on the Thermal-Decomposition of Ammonium Oxalate Monohydrate
The effects of gamma radiations on the kinetic parameters of the dynamic thermal decomposition-gasification reactions of ammonium oxalate monohydrate have been investigated using differential thermal analysis and thermogravimetry techniques. Kinetic analysis of the dynamic TG results are discussed in view of a composite integral method in comparison with the integral methods due to Coats and Redfern and to Ozawa. The activation parameters for the non-irradiated and irradiated samples are calculated and the results of the different methods of data analysis are compared and discussed.