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Thermochimica Acta, Vol.246, No.1, 1-10, 1994
Heat-Capacity Anomalies at the Verwey Transition of Fe-3(1-Delta)O-4
It is known that the order of the Verwey transition changes from first to second, and then to a higher order, as the value of delta increases in magnetite, Fe-3(1-delta)O-4. The associated heat capacity anomaly changes its shape and size, and it eventually becomes a broad hump, i.e. a higher order transition. An attempt was made, with some success, at recovering the observed changes in heat capacity anomaly in terms of the two-state approximation, a generalized extension of the Strassler-Kittel treatment. By changing the adjustable parameters as a smooth linear function of delta, a qualitative trend of the observed changes in heat capacity anomaly was reproduced.