Thermochimica Acta, Vol.286, No.1, 25-31, 1996
Nonisothermal Crystallization of La2O3-Center-Dot-B2O3-Center-Dot-2Geo(2) Glasses
The non-isothermal crystallization of lanthanum borogermanate glasses, of stoichiometry LaBGeO5 has been studied by differential thermal analysis. The phase that crystallizes during the DTA runs was identified by X-ray diffraction as the stillwellite-like LaBGeO5. In the glasses studied, crystallization from surface nuclei was found to be dominant. The activation energy of crystal growth, evaluated from DTA curves, was about 465 kJ mol(-1).