Thermochimica Acta, Vol.310, No.1-2, 87-94, 1998
Effect of NaCl on the excess enthalpies of binary liquid systems
The excess molar enthalpies h(1+23)(E), of ethanol+(water+NaCl), benzylalcohol+(water+NaCl), and cyclohexane+(methanol+NaCl) were measured at 298.15 K, those of methanol+(water+NaCl) at 298.15 and 323.15 K. An LKB flow microcalorimeter was used and a special flow-mix cell was developed with regard to the corrosive electrolyte solutions. Knowing the integral enthalpy of solution and the solution enthalpy at infinite dilution for a salt (3) in a solvent (2), the molar excess enthalpy h(123)(E), can be calculated.