Acylaziridinyl Ferrocene의 합성 및 혼합형 추진제 적용

홍명표; 이범재; 황갑성; 김창기; 박영철

Polymer(Korea), Vol.21, No.2, 302-308, March, 1997

Export Citation

Acylaziridinyl Ferrocene의 합성 및 혼합형 추진제 적용

Synthesis of Acylaziridinyl Ferrocene and Its Application for Composite Propellant

홍명표, 이범재, 황갑성, 김창기, 박영철

초록

Hydroxy-terminated polybutadiene (HTPB)/ammonium perchlorate (AP)계 혼합형 고체 추진제의 연소촉매와 결합제의 역할을 동시에 가지는 새로운 acylaziridinyl ferrocene 화합물로 1,1'-Ferrocenedicarbonyl-bis-[2-methylaziridine] (AAF)을 합성하였다. AP 존재 하에 AAF의 중합성을 1,1'-[1,3-phenylene dicarboxy]-bis-[2-methylaziridine]과 비교 관찰하였으며 이를 적용한 추진제의 공정성, 기계적 특성 및 연소특성을 고찰하였다.

1,1'-Ferrocenedicarbonyl-bis-[2-methylaziridine] (AAF) was synthesized as new acylaziridinyl ferrocene compound having both burning catalyst and bonding agent for hydroxy-terminated polybutadiene/ammonium perchlorate propellants. As AAF applied to propellant, polymerizability of AAF, processability, and mechanical and ballistic properties were systematically studied.

Keywords:AAF(acylarizidinyl ferrocene);Burning Catalyst;Bonding Agent;Mechanical Property;Composite Propellant

[References]

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Hori K, "Enhancement of Matrix/Filler Adhesion in HMX/AP/HTPB Composite Propellant," 18th International Annual Conference of ICT, Karlsruhe, Germany (1987)
Hori K, Propell. Explosives Pyrotech., 15, 99 (1990)
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[1] Oberth AE, "Principles of Solid Propellant Development," CPIA Publication 469 (1987)

[2] Fisher HM, "Multipurpose Additives for Composite Propellant," Report No. RK-TR-69-6, U.S. Army Missile Command (1969)

[3] Ayers OE, Hukins CW, "Multipurpose Additives for Composite Propellant Part II," Report No. RK-TR-70-8, U.S. Army Missile Command (1969)

[4] Bohneim-Maus J, "Structural Influences of Ferrocenes on Burn Rate Modification of Composite Rocket Propellant," 23th International Conference of ICT (1993)

[5] Gotzmer C, "Non-Migrating Ferrocene Modifiers for Composite Propellant," JANNAF Propulsion Meeting, CPIA Publication 300, vol. II, p. 475 (1979)

[6] Braun JD, U.S. Patent, 3,932,240 (1976)

[7] Raynal S, Doriath G, "New Functional Prepolymers for High Burning Rate Solid Propellants," AIAA-86-1594 (1986)

[8] Kishore K, Rajalingram P, J. Polym. Sci. C: Polym. Lett., 24, 471 (1986)

[9] Kishore K, Rajalingram P, J. Appl. Polym. Sci., 37, 2845 (1989)

[10] NASA Report No. SP-8064, "Solid Propellant Selection and Characterization," NASA (1971)

[11] Hori K, "Enhancement of Matrix/Filler Adhesion in HMX/AP/HTPB Composite Propellant," 18th International Annual Conference of ICT, Karlsruhe, Germany (1987)

[12] Hori K, Propell. Explosives Pyrotech., 15, 99 (1990)

[13] Kelly FN, "Propellants Manufacture, Hazards, and Testing," eds. by C. Boyars and K. Klager, American Chemical Society, Washington D.C. (1969)

[14] Klager K, Wrightson JM, "Mechanics and Chemistry of Solid Propellants," eds. by A.C. Eringen, H. Liebowitz, S.L. Koh, and J.M. Crowley, Pergamon Press (1967)