Filler-Polymer Interactions in Filled Styrene-Butadiene Rubber Compounds

Sung-Seen Choi

Korea Polymer Journal, Vol.9, No.1, 45-50, February, 2001

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Filler-Polymer Interactions in Filled Styrene-Butadiene Rubber Compounds

Sung-Seen Choi^†

Kumho Research and Development Center, 555, Sochon-dong, Kwangsan-gu, Kwangju 506-711, Korea

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Formation of bound rubber depends on the filler-polymer interactions including physical adsorption, chemisorption, and mechanical interaction. Bound rubbers consist of tightly and loosely bound ones. Styrene-butadiene rubber (SBR) is composed of styrene, 1,2-, cis-1,4-, and trans-1,4-units. Filler-polymer interactions of each components of SBR with fillers, carbon black and silica, were studied by analysis of microstructure of the bound rubber, Filler-polymer interaction of the 1,2-unit. with the fillers was found to be stronger than those of the other components and this phenomenon was shown more clearly in the tightly bound rubber.

[References]

Twiss DF, J. Soc. Chem. Ind., 44, 1067 (1925)
Sircar AK, Voet A, Rubber Chem. Technol., 43, 973 (1970)
Sperberg LR, Svetlik JF, Bliss LA, Ind. Eng. Chem., 41, 1607 (1949)
Dannberg EM, Rubber Chem. Technol., 59, 512 (1986)
Stickney PB, Falb RD, Rubber Chem. Technol., 37, 1299 (1964)
Meissner B, Rubber Chem. Technol., 48, 810 (1975)
Wolff S, Wang MJ, Rubber Chem. Technol., 65, 329 (1992)
Wolff S, Wang MJ, Tan EH, Rubber Chem. Technol., 66, 163 (1993)
Yatsuyanagi F, Kaidou H, Ito M, Rubber Chem. Technol., 72, 657 (1999)
Choi SS, Korea Polym. J., 7(4), 244 (1999)
Byers JT, Rubber World, 218(6), 38 (1998)
Wolff S, Wang MJ, Rubber Chem. Technol., 65, 329 (1992)
Boonstra BB, Cochrane H, Dannenberg EM, Rubber Chem. Technol., 48, 558 (1975)
Voet A, Morawski JC, Donnet JB, Rubber Chem. Technol., 50, 342 (1977)
Ou YC, Yu ZZ, Vidal A, Donnet JB, Rubber Chem. Technol., 67, 834 (1994)
Li Y, Wang MJ, Zhang T, Zhang F, Fu X, Rubber Chem. Technol., 67, 693 (1994)
Gorl U, Hunsche A, in Proceedings of the Rubber Division 150th Meeting, American Chemical Society, Paper No. 76 (1996)
Gorl U, Hunsche A, in Proceedings of the Rubber Division 151st Meeting, American Chemical Society, Paper No. 38 (1997)
Hashim AS, Azahari B, Rubber Chem. Technol., 71, 289 (1998)
Choi SS, J. Anal. Appl. Pyrolysis, 55, 161 (2000)
Choi SS, Bull. Korean Chem. Soc., 20, 1348 (1999)
Ohtani H, Ueda S, Tsukahara Y, Watanabe C, Tsuge S, J. Anal. Appl. Pyrolysis, 25, 1 (1993)
Bradna P, Zima J, J. Anal. Appl. Pyrolysis, 21, 207 (1991)
Radhakrishnan TS, Rao MR, J. Polym. Sci. Polym. Chem. Ed., 19, 3197 (1981)
Hacaloglu J, Ersen T, Ertugrul N, Fares MM, Suzer S, Eur. Polym. J., 33, 199 (1997)
Ghebremeskel GN, Sekinger JK, Hoffpauir JL, Hendrix C, Rubber Chem. Technol., 69, 874 (1996)
Choi SS, J. Anal. Appl. Pyrolysis, 57, 249 (2001)
OBrien J, Cashell E, Wardell GE, McBrierty VJ, Macromolecules, 9, 653 (1976)
Kenny JC, McBrierty VJ, Rigbi Z, Douglass DC, Macromolecules, 24, 436 (1991)
Legrand AP, Lecomte N, Vidal A, Haidar B, Papiper E, J. Appl. Polym. Sci., 46, 2223 (1992)
Guaita M, Br. Polym. J., 18, 226 (1986)
Choi SS, J. Anal. Appl. Pyrolysis, 55, 161 (2000)

[Referenced By]

[1] Twiss DF, J. Soc. Chem. Ind., 44, 1067 (1925)

[2] Sircar AK, Voet A, Rubber Chem. Technol., 43, 973 (1970)

[3] Sperberg LR, Svetlik JF, Bliss LA, Ind. Eng. Chem., 41, 1607 (1949)

[4] Dannberg EM, Rubber Chem. Technol., 59, 512 (1986)

[5] Stickney PB, Falb RD, Rubber Chem. Technol., 37, 1299 (1964)

[6] Meissner B, Rubber Chem. Technol., 48, 810 (1975)

[7] Wolff S, Wang MJ, Rubber Chem. Technol., 65, 329 (1992)

[8] Wolff S, Wang MJ, Tan EH, Rubber Chem. Technol., 66, 163 (1993)

[9] Yatsuyanagi F, Kaidou H, Ito M, Rubber Chem. Technol., 72, 657 (1999)

[10] Choi SS, Korea Polym. J., 7(4), 244 (1999)

[11] Byers JT, Rubber World, 218(6), 38 (1998)

[12] Wolff S, Wang MJ, Rubber Chem. Technol., 65, 329 (1992)

[13] Boonstra BB, Cochrane H, Dannenberg EM, Rubber Chem. Technol., 48, 558 (1975)

[14] Voet A, Morawski JC, Donnet JB, Rubber Chem. Technol., 50, 342 (1977)

[15] Ou YC, Yu ZZ, Vidal A, Donnet JB, Rubber Chem. Technol., 67, 834 (1994)

[16] Li Y, Wang MJ, Zhang T, Zhang F, Fu X, Rubber Chem. Technol., 67, 693 (1994)

[17] Gorl U, Hunsche A, in Proceedings of the Rubber Division 150th Meeting, American Chemical Society, Paper No. 76 (1996)

[18] Gorl U, Hunsche A, in Proceedings of the Rubber Division 151st Meeting, American Chemical Society, Paper No. 38 (1997)

[19] Hashim AS, Azahari B, Rubber Chem. Technol., 71, 289 (1998)

[20] Choi SS, J. Anal. Appl. Pyrolysis, 55, 161 (2000)

[21] Choi SS, Bull. Korean Chem. Soc., 20, 1348 (1999)

[22] Ohtani H, Ueda S, Tsukahara Y, Watanabe C, Tsuge S, J. Anal. Appl. Pyrolysis, 25, 1 (1993)

[23] Bradna P, Zima J, J. Anal. Appl. Pyrolysis, 21, 207 (1991)

[24] Radhakrishnan TS, Rao MR, J. Polym. Sci. Polym. Chem. Ed., 19, 3197 (1981)

[25] Hacaloglu J, Ersen T, Ertugrul N, Fares MM, Suzer S, Eur. Polym. J., 33, 199 (1997)

[26] Ghebremeskel GN, Sekinger JK, Hoffpauir JL, Hendrix C, Rubber Chem. Technol., 69, 874 (1996)

[27] Choi SS, J. Anal. Appl. Pyrolysis, 57, 249 (2001)

[28] OBrien J, Cashell E, Wardell GE, McBrierty VJ, Macromolecules, 9, 653 (1976)

[29] Kenny JC, McBrierty VJ, Rigbi Z, Douglass DC, Macromolecules, 24, 436 (1991)

[30] Legrand AP, Lecomte N, Vidal A, Haidar B, Papiper E, J. Appl. Polym. Sci., 46, 2223 (1992)

[31] Guaita M, Br. Polym. J., 18, 226 (1986)

[32] Choi SS, J. Anal. Appl. Pyrolysis, 55, 161 (2000)