화학공학소재연구정보센터
Journal of Chemical Physics, Vol.108, No.11, 4572-4581, 1998
Fractal kinetics and surface reactions
Simple models of bimolecular surface reactions occurring on a regular lattice are investigated by means of Monte-Carlo simulations. Fractal kinetics, observed in various steady-state regimes, appear to be due to the fractal nature of the adsorbate clusters generated by the microscopic mechanisms of the kinetic scheme. Two-site mechanism rates involve anomalous orders which are tentatively assigned to cluster properties defined in terms of ad-percolation specifics.