화학공학소재연구정보센터
Chemical Engineering Journal, Vol.81, No.1-3, 15-21, 2001
Evaluation of theoretical viscosity models for concentrated emulsions at low capillary numbers
The theoretical models for the viscosity of concentrated emulsions are reviewed. All models predict that the relative viscosity of an emulsion, at low capillary numbers, is a function of dispersed-phase volume fraction and viscosity ratio (ratio of dispersed-phase viscosity to continuous-phase viscosity). The predicted values of relative viscosity from different theoretical models are compared with a large amount of experimental data. The cell model of Yaron and Gal-Or [Rheol. Acta 11 (1972) 241] predicts the relative viscosities of emulsions reasonably well over a wide range of dispersed-phase volume fraction and viscosity ratio. The cell model of Choi and Schowalter [Phys. Fluids 18 (1975) 420] overpredicts the relative viscosities, especially at high values of dispersed-phase volume fraction. The Phan-Thien and Pham model [J. Non-Newtonian Fluid Mech. 72 (1997) 305] underpredicts the relative viscosities of emulsions at high values of dispersed-phase volume fraction. (C) 2001 Elsevier Science B.V. All rights reserved.