We investigate the effects of the flow-field configuration on the sooting characteristics of normal and inverse coflowing diffusion flames. The numerical model solves the time-dependent, compressible, reactive-flow, Navier-Stokes equations, coupled with submodels for soot formation and thermal radiation transfer. A benchmark calculation is conducted and compared with experimental data, and shows that computed peak temperatures and species concentrations differ from the experimental values by less than 10%, while the computed peak soot volume fraction differs from the experimental values by 10-40%, depending on height. Simulations are conducted for three normal diffusion flames in which the fuel/air velocities (cm/s) are 5/10, 10/10, and 10/5, and for an inverse diffusion flame (where the fuel and air ports have been reversed) with a fuel/air velocity of 10/10. The results show significant differences in the sooting characteristics of normal and inverse diffusion flames. This work supports previous conclusions from the experimental work of others. However, in addition, we use the ability of the simulations to numerically track soot parcels along pathlines to further explain the experimentally observed phenomena. In normal diffusion flames, both the peak soot volume fraction and the total mass of soot generated is several orders of magnitude greater than for inverse diffusion flames with the same fuel and air velocities. In normal diffusion flames, soot forms in the annular region on the fuel-rich side of the flame sheet, while in inverse flames, the soot forms in a fuel-rich region on top of the flame sheet. Surface growth is the dominant soot formation mechanism (compared to nucleation) for both types of flames; however, surface growth rates are much faster for normal diffusion flames compared to inverse flames. Soot oxidation rates are also much faster in normal flames, where the dominant soot-oxidizing species is OH, compared to inverse flames, where the dominant soot-oxidizing species is O-2. In the inverse flames, surface growth continues after oxidation has ceased, causing the peak soot volume fraction to be sustained for a long period of time, and causing the emission of soot, even though the quantity of soot is small. Comparison of soot formation among the three normal diffusion flames shows that the peak soot volume fraction and total mass of soot generated increases as the fuel-to-air velocity ratio increases. A larger fuel-ah velocity ratio results in a longer residence time from the nucleation to the oxidation stage, allowing for more soot particle growth. When the fuel-to-oxidizer ratio decreases, there is less time for surface growth, and the particles cross the flame sheet (where they are oxidized) earlier, resulting in decreased soot volume fraction. Published by Elsevier Science Inc.