Journal of Applied Polymer Science, Vol.80, No.4, 613-617, 2001
Heterogeneous polymerization of ethene with metallocene catalysts. A comparison of poly(organosiloxane) microgels and silica as support materials for MAO-type cocatalysts
Zirconocene dichloride and bis(n-butylcyclopentadienyl)zirconium dichloride are used as catalyst precursors for the heterogeneous polymerization of ethene. A methyl-substituted microgel as support material for heterogeneous cocatalysts on the basis of MAO is compared with different commercially available silica-supported cocatalysts. The catalyst performances and the properties of the obtained polyethenes show considerable differences.
Keywords:poly(organosiloxane) microgels;heterogeneous catalysis;metallocene catalysts;olefin polymerization;polyethene