In the paper, a new approach to the control of the selective catalytic reduction process of NOX is presented. The reduction process can be efficiently controlled using a combination of feed-forward and feed-back control structures. However, this approach requires expensive measurement equipment. It is shown that measurement of nitric oxide concentration at the input of the catalytic converter and measurement of the flue gas flow rate can be successfully substituted by corresponding "software sensors". The software sensors are based on simple mathematical models and on measurements of excess oxygen concentration in flue gas and the fuel flow rate which are usually parts of already available standard combustion control system equipment. In the paper the complete derivation of the required mathematical models is given, and the proposed new control structure is described. The structure is tested using simulation and implemented on an industrial pilot plant. (C) 2000 Elsevier Science Ltd. All rights reserved.