We have examined the steam reforming of n-butane on ceria. 1 wt% Pd/ceria, 1 wt% Pd/alumina, and 15 wt% Ni/silica between 573 and 873 K, with H2O:C ratios between 1.0 and 2.0. No stable rates could be observed on Ni/silica due to rapid coking under these conditions. While rates were stable on the other catalysts, Pd/ceria showed a much higher activity than either Pd/alumina or ceria individually. Of additional interest, CO2 :CO ratios were much higher on Pd/ceria and approached equilibrium. The reaction order for n-butane on Pd/ceria was 0.15. For H2O. reaction order changed from 0.6 to zero at the stoichiometric, n-butane:H2O ratio. It is suggested that the high activity of Pd/ceria for this reaction is due to a dual-function mechanism, in which ceria can be oxidized by H2O and then supply oxygen to the Pd.