Korean Journal of Chemical Engineering, Vol.18, No.4, 463-467, July, 2001
Characteristics of Carbon Dioxide Hydrogenation in a Fluidized Bed Reactor
E-mail:
Characteristics of CO2 hydrogenation were investigated in a fluidized bed reactor (0.052 m ID×1.5 m in height). Coprecipitated Fe-Cu-K-Al catalyst (d(p)=75-90 μm) was used as a fluidized solid phase. It was found that the CO2 conversion decreases but the CO selectivity increases, whereas the space-time-yield attains maximum values with increasing gas velocity. The CO2 conversion has increased, but CO selectivity has decreased with increasing hydrogenation temperature, pressure or H2/CO2 ratio in the fluidized bed reactor. Also, the CO2 conversion and olefin selectivity appeared to be higher in the fluidized bed reactor than those of the fixed bed reactor.
- Choi PH, Jun KW, Lee SJ, Choi MJ, Lee KW, Catal. Lett., 40(1-2), 115 (1996)
- Deckwer WD, Serpemen Y, Ralex M, Schmidt B, Ind. Eng. Chem. Proc. Des. Dev., 36, 231 (1982)
- Dry ME, Appl. Catal. A: Gen., 138(2), 319 (1996)
- Ellenberger J, Krishna R, Chem. Eng. Sci., 49(24), 5391 (1994)
- Fan LS, "Gas-Liquid-Solid Fluidization Engineering," Butterworths, Stoneham. MA (1989)
- Inui T, Hara H, Takeguchi T, Ichino K, Kim JB, Iwamoto S, Pu SB, Energy Conv. Manag., 38, S385 (1997)
- Kang Y, Shim JS, Kim SD, Ko MH, Kim SD, Korean J. Chem. Eng., 13(3), 317 (1996)
- Kang Y, Woo KJ, Ko MH, Cho YJ, Kim SD, Korean J. Chem. Eng., 16(6), 784 (1999)
- Kim SD, Kang Y, Chem. Eng. Sci., 52(21-22), 3639 (1997)
- Krishna R, Ellenberger J, Sie ST, Chem. Eng. Sci., 51(10), 2041 (1996)
- Nam SS, Lee SJ, Kim H, Jun KW, Choi MJ, Energy Conv. Manag., 38, S397 (1997)
- Riedel T, Claeys M, Schulz H, Schaub G, Nam SS, Jun KW, Choi MJ, Kishan G, Lee KW, Appl. Catal. A: Gen., 186(1-2), 201 (1999)
- Sanders E, Ledakowicz S, Deckwer WD, Can. J. Chem. Eng., 64, 133 (1986)
- Satterfield CN, Huff GA, Stenger HG, Carter JL, Madon RJ, Ind. Eng. Chem. Fundam., 24, 450 (1985)
- Steynberg AP, Espinoza RL, Jager B, Vosloo AC, Appl. Catal. A: Gen., 186(1-2), 41 (1999)
- Yan SR, Jun KW, Hong JS, Lee SB, Choi MI, Lee KW, Korean J. Chem. Eng., 16(3), 357 (1999)