Journal of Chemical Physics, Vol.108, No.5, 2228-2231, 1998
Induced orientational order in liquid layers
A density functional approach has been used to study the effect of an orientation dependent substrate potential on a simple fluid of linear particles with weak anisotropy. Within a model potential, it can be shown that orientational order can be induced within the range of the substrate interaction near the freezing temperature. This is superimposed on the usual density variation at the surface and can cause an unusual negative temperature variation of the surface tension.