화학공학소재연구정보센터
Journal of Chemical Physics, Vol.111, No.7, 3265-3273, 1999
Lubrication corrections for three-particle contribution to short-time self-diffusion coefficients in colloidal dispersions
It is shown that the standard treatment of lubrication effects in many-particle hydrodynamic interactions leads to divergent three-particle contributions to the short-time translational self-diffusion coefficient. To resolve the problem the improved method to account for lubrication is proposed. The translational and rotational self-diffusion coefficients of the Brownian semidilute suspension are then evaluated up to terms of the second order in volume fraction.