Journal of Chemical Physics, Vol.111, No.17, 8105-8114, 1999
Mathematical modeling of complex oscillatory phenomena during CO oxidation over Pd zeolite catalysts
A mathematical model, which simulates the complicated dynamic behavior experimentally observed during CO oxidation over Pd zeolite catalysts is presented. It describes the coupling of reaction rate oscillations, generated by various parts of the inhomogeneous catalytic layer through the gas phase. It can be shown, that the resulting dynamic behavior depends upon the difference between natural frequencies of local oscillators and the strength of coupling, which is defined mostly by the degree of conversion. Chaotic behavior could be identified under the condition of weak coupling for local oscillators with widely different natural frequencies. In the range of strong coupling the phenomenon of phase death has been obtained. A special type of intermittency chaos ("on-off" chaos) was observed in a small region of parameters under the conditions of strong coupling.