화학공학소재연구정보센터
Journal of Chemical Physics, Vol.111, No.18, 8298-8301, 1999
Correlation length and amplitude scaling in critical polymer solutions
We present a light scattering measurement of the correlation length for a series of critical solutions of polystyrene in methylcyclohexane with different molecular weights. Our results show that the correlation length xi similar to N(zeta)nu epsilon(-0.63), where N is the polymerization index and epsilon =(T-T-c)/T-c is the reduced temperature. The N exponent zeta(nu) is found to be 0.18+/-0.02, which is contrary to most earlier direct experimental results but in excellent agreement with theoretical predictions by de Gennes and Stepanow.