화학공학소재연구정보센터
Journal of Materials Science, Vol.35, No.13, 3409-3413, 2000
High-temperature thermoelectric properties of the sintered Bi2Sr2Ca1-xYxCu2Oy (x=0-1)
Electrical conductivity and Seebeck coefficient were measured in a temperature range of 320-1073 K for sintered samples of Bi2Sr2Ca1-xYxCu2Oy (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0). It has been found that the conduction behavior changes from n-type metallic to p-type semiconducting with increasing yttrium concentration. The power factors were in a range of 1.7-3.0 x 10(-5) Wm(-1) K-2 for the sample with x = 0.8, being maximized by the optimization of the yttrium concentration. The thermal conductivity for the sample with x = 0.8 was 0.73 Wm(-1) K-1 at 310 K, and decreased with increasing temperature. The values of thermoelectric figure of merit were estimated to be in a range of 3.4-4.8 x 10(-5) K-1 at temperatures of 320-673 K for the sample with x = 0.8.