Sigma = 19, [110] tilt grain boundaries have been observed to facet parallel to particular planes; the facets lie along ((3) over bar3 (1) over bar)(A)/(3 (3) over bar3 (1) over bar)(B), ((5)over bar>58>)(A)/7 (7) over bar4>)(B) and ((2) over bar2 (7) over bar)(A)/(4<(4)over bar5>)(B). The structural unit of the Sigma = 19 ((3) over bar3 (1) over bar>)(A)/(3 (3) over bar(1) over bar)(B) [110] boundaries consists of 5- and 7-member rings, which are similar to the core structure of a/2[110] edge dislocations. The polarities in each grain on either side of the boundaries has been confirmed by CBED methods; a lower number of anti-site type cross-boundary bonds occur along the boundaries compared to when the polarity of one grain is reversed. The presence of 7-member rings and anti-site cross-boundary bonds results in a more open atomic structure at the boundary, shortening the distance between the first and the second {331} atomic planes from the boundary plane by 40%.