Journal of Applied Polymer Science, Vol.79, No.1, 108-114, 2001
Viscoelastic characterization of semiconducting dodecylbenzenesulfonic acid doped polyaniline electrorheological suspensions
Dodecylbenzenesulfonic acid (DBSA)-doped polyaniline particles were synthesized via emulsion polymerization, and electrorheological (ER) fluids were prepared by dispersing the synthesized polyaniline particles in silicone oil. The viscoelastic properties of DBSA-doped polyaniline/silicone ail ER systems were examined using a vertical oscillation rheometer (VOR), which is designed for the rheological measurement of ER fluids, with a high voltage generator. Viscoelastic data obtained from the VOR were compared with those obtained from a commercial Physica rotational rheometer. The data from VOR were quite reliable in a broad range of both strain and frequency.
Keywords:electrorheological fluid;dodecylbenzensulfonic acid;polyaniline;vertical oscillation rheometer