Journal of Polymer Science Part A: Polymer Chemistry, Vol.37, No.19, 3723-3729, 1999
Dispersion polymerization of pyrrole using ethylhydroxyethylcellulose as a stabilizer
Oxidative polymerization of pyrrole has been studied using FeCl3 or (NH4)(2)S2O8 (APS) as oxidant, ethylhydroxyethylcellulose (EHEC) as a steric stabilizer and water or aqueous ethanol as the dispersion medium. Transmission electron micrographic images of the particles from the as-prepared dialysed dispersions in aqueous ethanol show small as well as large particles (about a decade larger) when FeCl3 is used as the oxidant but only large particles when APS is used as the oxidant. Small particles are not found when the dispersions are prepared in water, irrespective of the oxidant used. The particle size decreases with an increase in molecular weight of the stabilizer for the same stabilizer concentration. The minimum amount of stabilizer required to support dispersion polymerization decreases upon increasing the alcohol content of the medium.