The physical aging behavior of an isotropic amorphous polyimide possessing a glass transition temperature of approximately 239 degrees C was investigated for aging temperatures ranging from 174 to 224 degrees C. Enthalpy recovery was evaluated as a function of aging time following sub-T-g annealing in order to assess enthalpy relaxation rates, and time-aging time superposition was employed in order to quantify mechanical aging rates from creep compliance measurements. With the exception of aging rates obtained for aging temperatures close to T-g, the enthalpy relaxation rates exhibited a significant decline with decreasing aging temperature while the creep compliance aging rates remained relatively unchanged with respect to aging temperature. Evidence suggests distinctly different relaxation time responses for enthalpy relaxation and mechanical creep changes during aging. The frequency dependence of dynamic mechanical response was probed as a function of time during isothermal aging, and failure of time-aging time superposition was evident from the resulting data. Compared to the creep compliance testing, the dynamic mechanical analysis probed the shorter time portion of the relaxation response which involved the additional contribution of a secondary relaxation, thus leading to failure of superposition. Room temperature stress-strain behavior was also monitored after aging at 204 degrees C, with the result that no discernible embrittlement due to physical aging was detected despite aging-induced increases in yield stress and modulus.