Journal of Polymer Science Part B: Polymer Physics, Vol.38, No.6, 838-845, 2000
Dynamical observation of structural transition of polymers using an X-ray diffraction system with imaging plates. II. Crystalline transition of poly(butylene terephthalate)
Poly(butylene terephthalate) has two crystalline forms of alpha and beta. The or form is more stable and is transformed into the beta form by stretching. The alpha<->beta transition stress was measured at various temperatures with the use of an X-ray diffraction system with imaging plates, and the relationship between the transition stress and temperature was obtained. Further, using the X-ray diffraction system, the drawing behavior of the nearly amorphous, undrawn polymer film was observed by taking up dynamically a series of X-ray diffraction patterns while a film was being drawn. The alpha form never occurred during drawing at any temperature because the stress to draw the film exceeded the alpha-->beta transition stress.
Keywords:poly(butylene terephthalate);X-ray diffraction;imaging plates;stress-strain curve;phase transition;phase diagram