Journal of Polymer Science Part B: Polymer Physics, Vol.39, No.18, 2159-2167, 2001
Rheological properties and foam processability for blends of linear and crosslinked polyethylenes
The effect of blending crosslinked linear low-density polyethylene (cLLDPE) on the rheological properties and foam processability of linear low-density polyethylene was studied. A small addition of cLLDPE, which had a low density of crosslink points, enhanced strain-hardening behavior in the elongational viscosity to a great degree, although it had little effect on the steady-state shear viscosity. The enhanced strain hardening reduced heterogeneous deformation during foaming. As a result, a foam with a uniform cell size distribution was obtained.
Keywords:rheological properties;elongational viscosity;polymer blends;metallocene;linear low-density polyethylene (LLDPE);crosslinking;foaming