마이크로파 에너지에 의해 결정 크기가 조절된 유기 안료의 합성

정기석; 고진필; 박상보; 박찬영; 민성기; 권종호; 오인환; 박성수; Ki Suck Jung; Jin Phil Ko; Sang Bo Park; Chan Young Park; Seong Kee Min; Jong Ho Kwon; In Whan Oh; Seong Soo Park

Polymer(Korea), Vol.25, No.5, 609-616, September, 2001

Export Citation

마이크로파 에너지에 의해 결정 크기가 조절된 유기 안료의 합성

The Synthesis of Crystalline-Size Controlled Organic Pigment by Microwave Energy

정기석, 고진필, 박상보, 박찬영, 민성기, 권종호¹, 오인환¹, 박성수 ^†

부경대학교 화학공학부, 부산 608-739
¹송원칼라(주), 울산 울주군 원산읍 원산리 689-890

Ki Suck Jung, Jin Phil Ko, Sang Bo Park, Chan Young Park, Seong Kee Min, Jong Ho Kwon¹, In Whan Oh¹, and Seong Soo Park^†

Division of Chemistry Engineering, Pukyong national University, Pusan 608-739, Korea
¹Songwon Color Co, Wonsanri, Onsanup, Uljugun, Ulsan 689-890, Korea

E-mail:

초록

본 연구에서는 copper phthalocyanine (CuPc)을 높은 합성 수율로서 성공적으로 합성시킴에 따라 용매를 사용하는 고분자의 합성 분야에 마이크로파 기술의 응용 가능성을 제시하고자 하였다. 가정용 전자레인지의 용기를 개조시키고 마이크로파 출력 조절기를 부착시키는 방법으로 본실험에 사용되는 가변식 마이크로파 합성 장치를 자체 제작하였다. 화학 분석법, X선 회절장치(XRD), 주사형 전자현미경(SEM) 및 입도 분석법(PSA)을 이용하여 재래식 열 공정 및 마이크로파 공정을 사용하여 여러 조건하에서 합성된 시료들의 특성을 비교 분석하였다.

The application of microwave technology to synthesis of polymer in solvent media has been shown by the synthesis of copper phthalocyanine (CuPc). The increase of synthetic yield-was demonstrated sucessfully in this study. A power variable microwave synthetic system has been developed with modifying cavity of domestic microwave oven and attaching microwave power controller. The properties of the specimen synthesized at various condition under the conventional thermal processing and microwave processing has been characterized by the means of chemical analysis, X-ray diffractometry (XRD), scanning electron microscopy (SEM), and particle size analysis (PSA).

Keywords:phthalocyanine;microwave synthetic system;organic pigment.

[References]

Metaxas AC, Meredith RJ, "Industrial Microwave Heating", Peter Peregrinus Ltd., United Kingdom (1993)
Sutton WH, Am. Ceram. Soc. Bull., 67(10), 1656 (1988)
Caddick S, Tetrahedron, 51(38), 10403 (1995)
Kingston HM, Haswell SJ, "Microwave Enhanced Chemistry", Amer. Chem. Soc., Washington DC (1997)
Cablewski T, Faux AF, Strauss CR, J. Org. Chem., 59, 3408 (1994)
Strauss CR, Trainor RW, Aust. J. Chem., 48, 1665 (1995)
Chemat S, Aouabed A, Bartels PV, Esveld DC, Chemat F, J. Microwave Power Electromagnetic Energy, 34(1), 55 (1999)
McKeown NB, "Phthalocyanine Materials", Cambridge Univ. Press, United Kingdom (1998)
Kharisov BI, Blanco LM, Torres-Martinez LM, Garcia-Luna A, Ind. Eng. Chem. Res., 38(8), 2880 (1999)
Wu Y, Tian H, Chen K, Liu Y, Zhu D, Dyes Pigments, 37(4), 317 (1998)
Yang CH, Lin SF, Chen HL, Chang CT, Inorg. Chem., 19, 3541 (1980)
Law KY, Chem. Rev., 99, 449 (1993)
Herbst W, Hunger K, "Industrial Organic Pigments", VCH Publishers, New York (1987)
Tomio S, Kazuhiro M, Tadashi N, Motokazu S, Europian Patent, EP 0443107 A2 (1991)

[Referenced By]

[Related Articles]

[1] Metaxas AC, Meredith RJ, "Industrial Microwave Heating", Peter Peregrinus Ltd., United Kingdom (1993)

[2] Sutton WH, Am. Ceram. Soc. Bull., 67(10), 1656 (1988)

[3] Caddick S, Tetrahedron, 51(38), 10403 (1995)

[4] Kingston HM, Haswell SJ, "Microwave Enhanced Chemistry", Amer. Chem. Soc., Washington DC (1997)

[5] Cablewski T, Faux AF, Strauss CR, J. Org. Chem., 59, 3408 (1994)

[6] Strauss CR, Trainor RW, Aust. J. Chem., 48, 1665 (1995)

[7] Chemat S, Aouabed A, Bartels PV, Esveld DC, Chemat F, J. Microwave Power Electromagnetic Energy, 34(1), 55 (1999)

[8] McKeown NB, "Phthalocyanine Materials", Cambridge Univ. Press, United Kingdom (1998)

[9] Kharisov BI, Blanco LM, Torres-Martinez LM, Garcia-Luna A, Ind. Eng. Chem. Res., 38(8), 2880 (1999)

[10] Wu Y, Tian H, Chen K, Liu Y, Zhu D, Dyes Pigments, 37(4), 317 (1998)

[11] Yang CH, Lin SF, Chen HL, Chang CT, Inorg. Chem., 19, 3541 (1980)

[12] Law KY, Chem. Rev., 99, 449 (1993)

[13] Herbst W, Hunger K, "Industrial Organic Pigments", VCH Publishers, New York (1987)

[14] Tomio S, Kazuhiro M, Tadashi N, Motokazu S, Europian Patent, EP 0443107 A2 (1991)