화학공학소재연구정보센터
Macromolecules, Vol.33, No.16, 6060-6067, 2000
Kinetics of individual block copolymer island formation and disappearance near an absorbing boundary
We investigate the formation and coalescence of surface relief structures in symmetric diblock copolymers films of poly(styrene-b-2-vinylpyridine) (PS-PVP) on chemically patterned surfaces. The substrates have patterns of self-assembled monolayers (SAMs) produced by microcontact printing HO-terminated (HO-) SAM stripes alternating with H3C-terminated (H3C-) SAM stripes. The PS-PVP lamellae over the H3C-SAM have a defect-rich morphology compared to the film above the MO-SAM. These film sections above the H3C-SAM attract excess PS-PVP that would normally form islands on a uniform substrate. In the early stages of annealing waves of thickness develop from the H3C/HO-SAM boundary and propagate into the film over the MO-SAM. For a 3 mu m wide MO-SAM stripe a single line of excess copolymer breaks up into a single line of islands with a well-defined spacing along the grating. At long times these islands dissolve by transport of copolymer to the H3C-SAM stripe. The well-defined 2D geometry allows us to analyze the transport leading to this dissolution quantitatively. The rate-controlling process during the island dissolution is two-dimensional pressure relaxation.