화학공학소재연구정보센터
Journal of Chemical Physics, Vol.115, No.15, 6974-6978, 2001
The visible laser excitation spectrum of YbOH: The (A)over-tilde(2)Pi-(X)over-tilde(2)Sigma(+) transition
The (A) over tilde (2)Pi-(X) over tilde (2)Sigma (+) electronic transition of YbOH has been analyzed for the first time. Gas-phase YbOH was produced in a Broida-type oven by the reaction of ytterbium metal vapor with H2O2 vapor. Low-resolution spectra recorded with a broadband dye laser were used to examine the vibrational structure of the (A) over tilde-(X) over tilde system while high-resolution laser spectroscopy with a single-frequency dye laser was employed to obtain spectra of the 000-000 and 000-100 bands of (YbOH)-Yb-174 and the 000-000 band of (YbOH)-Yb-172 (where v(1) is the Yb-O stretching mode). The rotational analysis of the (A) over tilde (2)Pi-(X) over tilde (2)Sigma (+) transition demonstrates YbOH is a linear molecule, much like the alkaline-earth monohydroxides. Rotational and vibrational parameters are presented and the unusual behavior of the ground state spin-rotation splitting is discussed through a comparison with the isoelectronic molecule YbF.