Canadian Journal of Chemical Engineering, Vol.74, No.5, 695-705, 1996
Composition Modulation of the Fischer-Tropsch Synthesis over a Supported Cobalt Catalyst
Different cycling strategies are explored to see if carbon chain growth can be enhanced and methane formation suppressed. Of the strategies considered, bang-bang cycling between H-2 and CO feeds substantially increased the consumption of CO and H-2, but the formation of higher hydrocarbons and olefins was reduced. The best strategy for longer chain hydrocarbons suitable for jet or diesel fuels was found to be cycling between syngas mixtures. None of the cycling strategies was able to produce C-8+ or low-molar mass olefin yields that matched yields found in steady-state operation.
Keywords:CARBON-MONOXIDE HYDROGENATION;CO HYDROGENATION;HYDROCARBON SYNTHESIS;PRODUCT DISTRIBUTION;RUTHENIUM CATALYSTS;PERIODIC OPERATION;SELECTIVITY;DISPERSION;REACTORS