Journal of Physical Chemistry A, Vol.103, No.41, 8169-8172, 1999
Differential decay of states excited in zero-kinetic-energy spectroscopy
Anomalous intensity in zero-kinetic-energy pulsed-field-ionization (ZEKE-PFI) spectroscopy caused by differential decay of excited states during and immediately after pulsed excitation and before l-mixing, is considered. Changes by more than a factor of 2 or so are shown to be impossible under typical experimental conditions.