Journal of Physical Chemistry A, Vol.105, No.40, 9219-9221, 2001
Kinetic equations in Hamiltonian treatments
Chemical kinetic equations are easily cast in a Hamiltonian form, making them amenable to a wealth of established techniques. The formalism allows for canonical transformations to simplify the rate equations, enables application of standard perturbation methods, and provides an approach for finding system invariants. Each of these features is illustrated for nontrivial systems.