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Journal of Physical Chemistry B, Vol.104, No.25, 6081-6090, 2000
A theoretical study on turing patterns in electrochemical systems
We present theoretical studies on pattern formation in electrochemical systems with an S-shaped current potential curve (S-NDR systems) under potentiostatic control. Linear stability analysis and simulations of the reaction-migration equation give evidence that stationary patterns with a defined wavelength exist in a large parameter range. As it is the case for Turing structures, the patterns form due to an interplay of short-range activation and long-range inhibition. It is shown that the constraint on the ratio of the diffusion constants of activator and inhibitor in reaction-diffusion equations transforms into a condition involving diffusion and migration lengths of the system. This condition is fulfilled in practically all electrochemical systems. The experimental parameters under which the patterns form should be readily accessible.