Journal of Physical Chemistry B, Vol.105, No.12, 2360-2364, 2001
Calculating the influence of external charges on the photoluminescence of a CdSe quantum dot
The influence of external charges on the radiative recombination rate of an electron-hole pair in a CdSe quantum dot is investigated via atomistic empirical pseudopotential calculations. It is found that, when a negative external charge is near the surface of a CdSe quantum dot, its Coulomb potential could be strong enough to pull the hole away from the electron and results in a reduction of the radiative recombination rate by a factor of 70. Distance, direction, charge number, and charge type dependences of this effect are investigated.