Journal of Physical Chemistry B, Vol.105, No.28, 6638-6641, 2001
Quantum Smoluchowski equation II: The overdamped harmonic oscillator
The quantum Smoluchowski equation is an equation for the coordinate-diagonal elements of the density operator, and it is identical to the classical Smoluchowski equation. Here, the leading finite-friction correction to the quantum Smoluchowski equation is derived, for the particular case of the overdamped harmonic oscillator. It is in fact a quantum correction, different from the well-known classical correction, and it dominates the classical correction in the strong friction regime.