Catalysis Letters, Vol.29, No.3-4, 349-359, 1994
Platinum Sulfated Zirconia - Infrared Study of Absorbed Pyridine
Pyridine adsorption on sulfated zirconia (SO4(2-)-ZrO2) provides evidence for infrared bands characteristic of both Bronsted and Lewis acid sites. Samples treated at 100-degrees-C retain water and have a higher fraction of Bronsted acidity than when the sample is treated at 400-degrees-C. The fraction of Bronsted acid sites observed for SO4(2-)-ZrO2 is the same in the presence or absence of supported Pt. Based on pyridine adsorption, exposure to gaseous hydrogen at 100 or 150-degrees-C did not significantly alter the fraction of Bronsted acid sites following the exposure to hydrogen.
Keywords:X-RAY-DIFFRACTION;PHASE-TRANSFORMATION;CATALYTIC ACTIVITY;CRYSTAL-STRUCTURES;HIGH-TEMPERATURE;OXIDE;ZRO2;ISOMERIZATION;ACIDITY;HYDROGEN