Surface tension, viscosity, intradiffusion, and interdiffusion measurements have been performed on aqueous solutions of sodium octyl sulfonate, sodium decyl sulfonate, and sodium undecyl sulfonate, in the presence of poly(vinylpyrrolidone) at 1% why. The experimental measurements for each ternary system were performed in a range of surfactant concentration including the binary critical micelle concentration of the surfactant. The overall picture of the properties studied suggests the absence of a specific interaction between poly(vinylpyrrolidone) and alkylsulfonate surfactants. The experimental diffusion coefficients can be interpreted in terms of an "excluded volume" effect produced by the presence of the polymer in solution.