Inorganic Chemistry, Vol.39, No.15, 3428-3429, 2000
On the failure to observe isotropic electron paramagnetic resonance spectra for certain chromium(I) carbonyl complexes
Although isotropic EPR spectra have often been states and consequent Jahn-Teller distortions, such reported for Cr(I) complexes with degenerate ground spectra have not been reported for cis-dicarbonyl or fac-tricarbonyl complexes of Cr(I). The most likely explanation is that ground states are subject to an approximate accidental degeneracy, probably modulated by a ligand bending vibrational mode, thus providing an efficient spin-lattice relaxation pathway. [GRAPHICS]