The reaction of manganese(II) and pyridine derivatives such as 3-methylpyridine (S-Mepy) and 3,4-dimethylpyridine (3,3-Dmepy) led to the new one-dimensional systems trans-[Mn(3-Mepy)(2)(N-3)(2)](n) (1) and trans-[Mn(3,4-Dmepy)(2)(N-3)(2)](n) (2). Compound 1 crystallizes in the monoclinic system, space group P2(1)/n, a = 11.201(3) Angstrom, b = 14.499(4) Angstrom, c = 14.308(4) Angstrom, Z = 6, and compound 2 crystallizes in the triclinic system, space group P (1) over bar, a = 11.502(4) Angstrom, b = 14.246(5) Angstrom, c = 16.200(8) Angstrom, Z = 6. The two compounds show the same general one-dimensional arrangement of double azido bridges between neighboring manganese atoms with the unprecedented -Mn-(mu (1,3)-N-3)(2)-Mn-(mu (1,3)-N-3)(2)-Mn-(mu (1,1)-N-3)(2)-Mn- sequence. Susceptibility and magnetization measurements reveal a ferrimagnetic-like behavior derived from the topology of the chain. A model of the Heisenberg chain, comprising classical spins coupled through alternating exchange interactions J(1)J(1)J(2)... is proposed to describe the magnetic behavior.